Essays on Dichloromethane

Iridium organometallic complexes

Introduction Iridium organometallic complexes are applied as catalysts, light-emitting diodes, dye-sensitized solar cells, and luminescent agents for cells imaging.1 Due to the wide application area, the scientists perform research on preparation, characterization and physical and chemical properties of iridium organometallic complexes.

The oxidation state in complex compound refers to the charge of the metal, which it would have in a simple ionic compound. The configuration of d-orbitals (dn) indicates the number of valence electrons in free metal of the same oxidation state. The iridium electronic configuration is [Xe] 4f145d76s2, yet the s-electrons transfer to d-orbital to form 5d9. The ...

Introduction

Reduction reactions are very important in chemistry as they are effective processes for synthesizing new compounds from existing ones. In organic chemistry, a compound is said to be reduced if it acquires new hydrogen. There are diverse reagents for carrying our reduction reactions. Two of these are sodium borohydride (NaBH4) and lithium aluminum hydride (LiAlH4) - the latter is a more powerful reducing agent compared to the former. In this experiment, NaBH4 was used to reduce p-Nitrobenzaldehyde to form p-Nitrobenzyl alcohol. NaBH4was used over LiAlH4 in this experiment, because LiAlH4 would also reduce the nitro group of the aldehyde.

Experimental:

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