Iridium organometallic complexes
Introduction Iridium organometallic complexes are applied as catalysts, light-emitting diodes, dye-sensitized solar cells, and luminescent agents for cells imaging.1 Due to the wide application area, the scientists perform research on preparation, characterization and physical and chemical properties of iridium organometallic complexes.
The oxidation state in complex compound refers to the charge of the metal, which it would have in a simple ionic compound. The configuration of d-orbitals (dn) indicates the number of valence electrons in free metal of the same oxidation state. The iridium electronic configuration is [Xe] 4f145d76s2, yet the s-electrons transfer to d-orbital to form 5d9. The ...
